This troper is shocked this page didn't already exist. I don't even know where to start, this show is so fetishy. I'm hoping this page will be a "if you build it, they will come" situation.
You've got the sciencey, redheaded skeptic in the form of Dana Scully. You've got Fox Mulder, the adorable, obsessive believer who's eyes implore you to trust him. Throw in all manner of paranormal stuff, along with some bondage on both sides, and the squiggly moments practically write themselves. Not to mention the show is super entertaining, ahead of its time, and often awesome on its own merits. It's on Netflix, go watch it if you haven't seen it already. I'm dead serious.